Fe3O4是由离子构成的吗 如果是由分子构成那么为什么也是含有金属元素的化合物呢

来源:百度知道 编辑:UC知道 时间:2024/06/04 05:05:44
因为看到有的人说,含金属元素的化合物由离子构成
Fe3O4不是由一个1个Fe3O4分子构成的吗

Fe3O4的确是离子构成的,但是你看到的说法是完全错误的, 含金属元素的化合物不一定由离子构成
等轴晶系,a0=0.8396nm;Z=8。反尖晶石型结构。即1/2的Fe3 和全部的Fe2 占据八面体位置,另1/2的Fe3 占据四面体位置。晶格常数a0随Al3 、Cr3 、Mg2 替代量的增大而减小;随Ti4 、Mn2 的替代量增高而增大。
出处:http://baike.baidu.com/view/23118.htm
Structure
Fe3O4 has a cubic inverse spinel structure which consists of a cubic close packed array of oxide ions where all of the Fe2+ ions occupy half of the octahedral sites and the Fe3+ are split evenly across the remaining octahedral sites and the tetrahedral sites.

Both FeO and γ-Fe2O3 have a similar cubic close packed array of oxide ions and this accounts for the ready interchangeability between the three compounds on oxidation and reduction as these reactions entail a relatively small change to the overall structure.[2] Fe3O4 samples can be non-stoichiometric.[2]

The ferrimagnetism of Fe3O4 arises because the electron spins of the FeII