UC知道请好心人帮我翻译，我很着急
来源：百度知道 编辑：UC知道 时间：2024/06/25 10:42:57
During the synthesis, ANI was added dropwise into the solution of MA and oxidant in HClaq (synthetic path A)or oxidant was added dropwise into the solution of MA and ANI in HClaq (synthetic path B).Synthesized emeraldine salts (ES) of SPAN were reduced to leucoemeraldine bases(LB)with hydrazine hydrate (Fluke), evaporated in a rotatory evaporator at 50ºC, residue was then washed with methanol and dried.
Furier transform infrared (FT-IR) absorbtion spectra of ES pellets with KBr were measured by Perkin-Eliner 1725X spectrometer. 7% solutions of the samples were prepared for NMR measurements in the mixture of NMP, triethylamine (TEA) and DMSO-d6 in the weight ratio 73:7:20.NMR spectra were measured by Varian VXR 300 MHz and INOVA 600 MHz NMR spectrometers. Conductivities of pressed ES were measured by impedance spectroscopy. The molecular masses were measured by GPC with Mixed D PL 5µ-gel column using the mixture of NMP, TEA and LiCl in weight ratio 100:0.5:0.5
Furier transform infrared (FT-IR) absorbtion spectra of ES pellets with KBr were measured by Perkin-Eliner 1725X spectrometer. 7% solutions of the samples were prepared for NMR measurements in the mixture of NMP, triethylamine (TEA) and DMSO-d6 in the weight ratio 73:7:20.NMR spectra were measured by Varian VXR 300 MHz and INOVA 600 MHz NMR spectrometers. Conductivities of pressed ES were measured by impedance spectroscopy. The molecular masses were measured by GPC with Mixed D PL 5µ-gel column using the mixture of NMP, TEA and LiCl in weight ratio 100:0.5:0.5
在合成，新华社是补充，滴成的解决马和氧化剂在hclaq （合成路径a ）或氧化剂的补充是滴到解决马和新华社在hclaq （合成路径二） 。合成emeraldine盐（安老服务）的跨度减少到leucoemeraldine基地（磅）与水合肼（福禄克） ，蒸发在一个旋转蒸发器在50 º C符合，残留当时水洗与甲醇和干果。furier变换红外（红外光谱）的吸收光谱部微丸与溴化钾测量珀金- eliner 1725x谱仪。 7 ％的解决方案的样品准备，核磁共振测量在混合nmp ，三乙胺（茶）和二甲基亚砜- D6中，在重量比为73:7:20 。 NMR谱测定瓦里安vxr 300兆赫和600兆赫的inova核磁共振分光计。导压部测量阻抗谱。分子群众测量通过GPC与混合d特等5 μ -凝胶柱使用的混合物nmp ，茶叶和氯化锂在重量比为100:0.5:0.5作为淋洗液