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The key compositional parameters involved in developing addition-curable silicone
PSAs include variations in the functional group type (SiH or Si-Vi), the number
of functional groups and molecular weights of the polymer, crosslinker and MQ
resin. An additioncure silicone PSA composition may also include organic diluents
and additives for specific requirements, e.g., for lowering the thermal expansion coefficient,
enhancing anchorage with the substrate, or improving high-temperature
properties. Temperature requirement for curing these silicone PSAs is also lower,
thus allowing the use of temperature-sensitive substrates. However, addition-cured
silicone PSA systems do suffer from generally lower heat stability than peroxide
systems. To overcome this deficiency, some patents describe improved compositions
that utilize peroxide and addition dual-cure mechanisms or the use of antioxidants
to improve high-temperature performance [9, 10,

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