谁能帮忙翻译一下 感激不尽!

来源:百度知道 编辑:UC知道 时间:2024/09/21 08:21:36
邻菲罗啉及其衍生物是一些超分子化合物的重要组成部分,以1,10-邻菲罗啉为配体的络合物具有良好的光学性质,可作为光敏计和光催化剂。1,10-邻菲罗啉-5,6-二酮作为稠杂环共轭配体,既具有良好的配位特性,又是重要的有机合成反应中间体,由该化合物的衍生物与金属离子形成的配合物可以用于抗肿瘤药物、DNA探针、非线性光学材料、超分子组装分子骨架、自旋交叉配合物等许多领域,因而对于它的合成研究引起了有关研究人员的高度重视。本论文以1,10-邻菲罗啉为起始原料,冰浴状态下在三颈烧瓶中加入浓硫酸,搅拌,依次加入溴化钾和浓硝酸,室温搅拌,升温至130℃,恒温反应经氧化合成1,10-邻菲罗啉-5,6二酮,并通过一系列的对比实验探索得到本实验的反应条件为:反应温度130℃、反应时间2h、浓硫酸和浓硝酸的加入量为70:35,产率为84.11%。

Phenanthroline and its derivatives supramolecular compounds are an important part of a 1,10 - phenanthroline ligand complex to have good optical properties, can be used as a catalyst for light meter and light. 1,10 - phenanthroline -5,6 - dione as a thick heterocyclic ligand conjugate, both characteristics of a good coordination is also important intermediates in organic synthesis reaction, the derivatives of the compounds with the metal ion complexes formed can be used for anti-cancer drugs, DNA probes, non-linear optical materials, supramolecular assembly of the molecular skeleton, Spin Crossover Complex and many other fields, which for its synthesis of research on the cause of the high degree of importance. In this paper, to 1,10 - phenanthroline used as starting material under the ice bath three neck flask by adding concentrated sulfuric acid, stirring, followed by adding potassium bromide and concentrated nitric acid at room temperature, stirring, heating to 130 ℃, reaction tem