UC知道高手翻译这一段
来源：百度知道 编辑：UC知道 时间：2024/06/08 00:39:56
During the EED of a meso or a prochiral compound,
the enzymatic reaction takes place faster at one of
the enantiotopic groups or faces of the substrate, thus
affording the two enantiomers of the product in unequal
amounts. This different rate of reaction arises
from the different energy of the diastereomeric transition
states between the enzyme and the substrate
along the reaction coordinate (¢¢Gq), and which can
be related to the enantioselectivity of the reaction by
means of eq 1, where E is the parameter that quantifies
the enantioselectivity displayed by the enzyme
in the EED. Despite the different names used for
this parameter, viz. “selectivity of the reaction” or
“prochiral selectivity”, we believe that there is no
contradiction in using the term “enantiomeric ratio”,
with the same sense it is used in the enzymatic KR
of racemic mixtures.
the enzymatic reaction takes place faster at one of
the enantiotopic groups or faces of the substrate, thus
affording the two enantiomers of the product in unequal
amounts. This different rate of reaction arises
from the different energy of the diastereomeric transition
states between the enzyme and the substrate
along the reaction coordinate (¢¢Gq), and which can
be related to the enantioselectivity of the reaction by
means of eq 1, where E is the parameter that quantifies
the enantioselectivity displayed by the enzyme
in the EED. Despite the different names used for
this parameter, viz. “selectivity of the reaction” or
“prochiral selectivity”, we believe that there is no
contradiction in using the term “enantiomeric ratio”,
with the same sense it is used in the enzymatic KR
of racemic mixtures.
在电火工品的一个中或前手性化合物
酶促反应发生在快之一
该手性团体或面临的衬底，因此
让两个对映体的产品在不平等
数额。这种不同的反应速率的出现
从不同能源的过渡映
各国之间的酶和衬底
沿反应坐标（ ¢ ¢宾馆） ，并能
与该对映选择性的反应
手段情商1 ，其中E是参数量化
该选择性展示出来的酶
在电火工品。尽管有不同的名称，用于
这个参数，即。 "选择性反应"或
"手性选择性" ，我们认为并不存在
矛盾使用的术语是"对映体比率" ，
具有相同意义上讲，它是用来在酶法氪
消旋混合物。