UC知道一小段生物化学的文章摘要,19号之前要其翻译
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是篇老的摘要了,中国知网上的一本<有机化学>期刊1991年第5期的一篇文献,谁有登陆号可以看到原文的帮忙找一下,翻译一下.我们的考试题目.急
手性桃潜蛾性信息素的新合成路线 陈子康;祝钧;成莹; 530-533
题目:A New Approach for the Synthesis of Chiral Sex Pheromone of Peach Leaf miner Moth
摘要:The enantiomeric 14-methyl-1-octadecenes were prepared by cross coupling reaction between the Grignard reagent of 12-Chloro-1-dodecene from 10-undecenoic acid and the enantiomeric 1-Bromo-2-methylhexane from corresponding (R) or (S) 2-methylhexanoic acidunder the catalysis of Li_2CuCl_4,The overall yield of the each enantiomer is about 30% fromthe racemic 2-methylhexanoic acid and the optical purity is approximately 100%.The (S)-enantiomer has showed strong bio-activity as the sex pheromone of peach leafminer moth in field tests.
万谢
手性桃潜蛾性信息素的新合成路线 陈子康;祝钧;成莹; 530-533
题目:A New Approach for the Synthesis of Chiral Sex Pheromone of Peach Leaf miner Moth
摘要:The enantiomeric 14-methyl-1-octadecenes were prepared by cross coupling reaction between the Grignard reagent of 12-Chloro-1-dodecene from 10-undecenoic acid and the enantiomeric 1-Bromo-2-methylhexane from corresponding (R) or (S) 2-methylhexanoic acidunder the catalysis of Li_2CuCl_4,The overall yield of the each enantiomer is about 30% fromthe racemic 2-methylhexanoic acid and the optical purity is approximately 100%.The (S)-enantiomer has showed strong bio-activity as the sex pheromone of peach leafminer moth in field tests.
万谢
一种新方法，为合成手性性信息素桃潜叶蝇蛾
摘要：对映体14 -甲基- 1 - octadecenes编写了交叉耦合反应之间的格氏试剂12 -氯- 1 -十二烯由10 - undecenoic酸和对映体1 -溴- 2 - m ethylhexane从相应的（ R ）或（ 2 ） - methylhexanoic acidunder催化li_2cucl_4 ，总收率为每对映体，是约30 ％ fromthe消旋2 - methylhexanoic酸和光学纯度大约是100 ％ 。 （ ） -对映体有较强的生物活性作为性信息素桃叶蛾在实地测试。