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4. Conclusion
In this study, we have characterized several Li1+yNix
Co1 2xMnxO2 which are Co-less and/or Li rich composition.
The cell performance depended on the composition. It
appeared that the change of electrochemical property (cell
performance) associated with composition variations were
closely related to both the structural disorder (cation mixing mixing)
and the electrical conductivity (volume resistivity) for
Li1+yNixCo1 2xMnxO2.
From results on XANES spectra, only Ni K-edge showed
an edge shift to higher energy due to the oxidation of Ni as
either Co content (1 2x) or excess Li content (y) increased.
These results indicate that part of Ni was oxidized from Ni2+
to Ni3+. The results of lattice parameter measurement showed
the unit cell size decreased as either Co content (1 2x) or
excess Li content (y) increased. It is assumed that these results
were caused by the change from Ni2+ to the smaller N
In this study, we have characterized several Li1+yNix
Co1 2xMnxO2 which are Co-less and/or Li rich composition.
The cell performance depended on the composition. It
appeared that the change of electrochemical property (cell
performance) associated with composition variations were
closely related to both the structural disorder (cation mixing mixing)
and the electrical conductivity (volume resistivity) for
Li1+yNixCo1 2xMnxO2.
From results on XANES spectra, only Ni K-edge showed
an edge shift to higher energy due to the oxidation of Ni as
either Co content (1 2x) or excess Li content (y) increased.
These results indicate that part of Ni was oxidized from Ni2+
to Ni3+. The results of lattice parameter measurement showed
the unit cell size decreased as either Co content (1 2x) or
excess Li content (y) increased. It is assumed that these results
were caused by the change from Ni2+ to the smaller N
4 。结论
在这项研究中，我们有几个特点Li1 + yNix
Co1 2xMnxO2这是联合少和/或李丰富的成分。
该电池的性能取决于组成。它
看来，变化的电化学性能（细胞
性能）与人组成的变化
密切相关的结构性障碍（阳离子混合搅拌）
和电导率（体积电阻）的
Li1 + yNixCo1 2xMnxO2 。
从结果XANES谱，只有镍K -边显示
优势转向更高的能源由于氧化镍作为
要么合作内容（ 1倍） ，或超过李含量（ Y ）的增加。
这些结果表明，部分氧化镍是从镍离子
以Ni3 + 。结果晶格参数测量显示
晶胞尺寸减少或者合作内容（ 1倍） ，或
过量李含量（ Y ）的增加。据推测，这些结果
人所造成的变化，镍离子的小Ni3 + 。印第安纳州
总之，这些实验结果表明，减少
体积电阻密切相关的增加
Ni3 +浓度Li1 + yNixCo1 2xMnxO2 。
不懂
4.在这项研究过程中的结论，我们已经表现是公司较少和/或李富有的组成的几Li1 yNix Co1 2 xMnxO2的特性。 小屋性能取决于组成。 似乎电化学的财产(小屋性能)的变化被联系 随着组成变化与结构的紊乱(阳离子混合混合)和Li1 yNixCo1 2 xMnxO2的电传导性(卷电阻率)密切相关。 从对XANES光谱的结果， 只镍K 边缘显示 一边缘给高能移动由于镍的氧化作为或者过度李满足(y)增加的公司内容(1 2 x)。 这些结果表明镍的部分被从Ni2 氧化到Ni3。 格子参数测量的结果显示单位小屋尺寸被减少 作为或者公司内容(1 2 x)，过度李满足(y)增加。 可以认为这些结果从Ni2到更小的Ni3通过变化被引起。 总之，这些实验结果表明reductio