UC知道化学英语在线翻译 谢谢了
来源：百度知道 编辑：UC知道 时间：2024/05/28 13:54:53
Cyclic voltammetry of derivative 7 in acetonitrile
exhibits two reversible oxidation waves, E1:2(1) 0.49 V
and E1:2(2) 0.76 V (versus Ag:AgCl), almost identical
to the values obtained for dimethylthio-TTF (E1:2(1)
0.45 V; E1:2(2) 0.76 V). The structures of derivatives
3, 4 and 7 were determined by X-ray diffraction
measurements7 of single crystals. The crystal structure
of 7 (Fig. 1) shows no intermolecular interactions,
although the stack is segregated along a diagonal axis.
The interplanar distances between the planes of pyridine–
pyridine and TTF–TTF are longer than 5.7 A, .
Alkylation of 7 is facile using 3–4-fold excess of methyl
iodide at room temperature in acetonitrile or acetone,
from which product 8 precipitates as black crystals. Salt
8 exhibits an ICT absorption band at lmax 572 nm in
ethanol, which does not correspond to any of the TTF
or pyridinium moieties, and obeys the Beer–Lambert
la
exhibits two reversible oxidation waves, E1:2(1) 0.49 V
and E1:2(2) 0.76 V (versus Ag:AgCl), almost identical
to the values obtained for dimethylthio-TTF (E1:2(1)
0.45 V; E1:2(2) 0.76 V). The structures of derivatives
3, 4 and 7 were determined by X-ray diffraction
measurements7 of single crystals. The crystal structure
of 7 (Fig. 1) shows no intermolecular interactions,
although the stack is segregated along a diagonal axis.
The interplanar distances between the planes of pyridine–
pyridine and TTF–TTF are longer than 5.7 A, .
Alkylation of 7 is facile using 3–4-fold excess of methyl
iodide at room temperature in acetonitrile or acetone,
from which product 8 precipitates as black crystals. Salt
8 exhibits an ICT absorption band at lmax 572 nm in
ethanol, which does not correspond to any of the TTF
or pyridinium moieties, and obeys the Beer–Lambert
la
在acetonitrile中循环的伏安法的派生物7展示几乎和为 dimethylthio-TTF得到价值观完全相同二可翻转氧化波 ,E1:2(1)0.49 V和E1:2(2)0.76 V(对Ag:AgCl)E1:2(1)0.45 V;E1:2(2)0.76 V.派生物3,4和7的结构被单一的水晶的X光衍射measurements7决心.虽然堆存在沿着一对角线的轴隔离,7的水晶结构((Fig. 1)展示没有分子间的相互作用.interplanar 与5.7 A相比更长pyridine?C吡啶和TTF?CTTF公亩的飞机之间的距离.Alkylation的7是易做到的使用3?C4- 褶印过多的在从8作为黑水晶促成哪一个产品acetonitrile金色丙酮中甲基碘化物阿特室温.Salt 8在lmax 572nm在朝派乙醇,其不与TTF或者pyridinium一半任何相符和守 Beer?CLambert法的展示一ICT吸收带.这个乐队的位置是有支付力受抚养者:一在DMSO解决方案((540 nm)中蓝移的和一在甲叉二氯((618 nm)中红移的被注意到.二可翻转氧化波被为这种化合物在更高潜力((E1:2(1)0.58 V和E1:2(2)0.81 V(对 Ag:AgCl))方面同意电子注意到接受取代基的本质.8的光化作用的小道具是和涉及trimethyl TTF赠送人unit8类似物相似和将其它地方被详细讨论.
4-fold excess of KpnI